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Lecturer(s)
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Kalová Jana, doc. RNDr. Ing. Ph.D.
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Course content
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1. Basic thermodynamic relations between thermophysical properties of fluids 2. The virial equaition of state 3. Cubic and generalized van der Waals equation of state 4. The corresponding-states principle 5. Termodynamic behaviour of fluids near critical points 6. Multi-parameter equations of state 7. Phase behaviour of fluids 8. Size dependence of the surface tension 9. Experimental methods for measuring thermophysical properties 10. Methodology of creating state equations 11 Thermophysical properties of water 12. Metastable states of water, supercooled water 13. Equations of the vapour pressure of water
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Learning activities and teaching methods
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Monologic (reading, lecture, briefing), Individual preparation for exam, Individual tutoring
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Learning outcomes
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The goal of this course is to acquaint students with the new approaches to the descriptions of thermophysical properties of fluids. Currently, there is a large amount of thermophysical data. The problem is their computer processing and evaluation. In this course, students will study the methodology of data processing, in the context of some specific descriptions of the properties of fluids, for example, with knowledge of the properties of supercooled water.
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Prerequisites
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knowledge corresponding to the scope covered by the courses Thermodynamics and statistical physics is required
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Assessment methods and criteria
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Oral examination, Student performance assessment, Interim evaluation
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Recommended literature
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Fuentevilla, D. A. Scaled Parametric Equation of State for the Liquid-Liquid Critical Point in Supercooled Water. University of Maryland, 2007.
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Goodwin, A. R. H.; Sengers, J. V.; Peters, Cor J. Applied thermodynamics of fluids. Cambridge : RSC Publishing, 2010. ISBN 978-1-84755-806-0.
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Hong Wei Xiang. The Coresponding-States Principle: Thermodynamic, Transport, Surface Properties of Fluids. Elsevier Science, 2005.
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Meier, G. H. Thermodynamics of surfaces and interfaces : concepts in inorganic materials. First published. Cambridge : Cambridge University Press : MRS Materials research Society, 2014. ISBN 978-0-521-87908-8.
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Orbey, H., Sandler, S. I.. Modeling Vapor-Liquid Equilibria. Cubic Equations of State and Their Mixing Rules. Cambridge University Press, 1998.
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Span, R. Multiparameter Equations of State, An accurate source of Thermodynamic Property Data. Springer, 2000.
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