| Course title | Physical Chemistry I |
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| Course code | UCH/105 |
| Organizational form of instruction | Lecture + Lesson |
| Level of course | Bachelor |
| Year of study | not specified |
| Frequency of the course | In each academic year, in the winter semester. |
| Semester | Winter |
| Number of ECTS credits | 5 |
| Language of instruction | Czech |
| Status of course | Compulsory |
| Form of instruction | unspecified |
| Work placements | unspecified |
| Recommended optional programme components | None |
| Lecturer(s) |
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| Course content |
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Content of lectures: Physical states of matter (ideal and real gases - equation of states , virial the theorem of corresponding states , liquids - evaporation , saturated vapor pressure , solids - crystal lattice, isomorphism and polymorphism , X-ray) Zero and the first law of thermodynamics (work , heat , state and stateless quantities, reversible and irreversible changes , enthalpy , heat capacity , heat of reaction,the reaction heat of formation , thermochemical equations , Hess law , Kirchhoff law , the maximum combustion temperature) Second and third law of thermodynamics ( isothermal and adiabatic process , Carnot cycle , entropy in the classical concept of entropy irreversible processes , Helmoholz and Gibbs function for reversible and irreversible changes , Maxwell relations , expansion of gas in a vacuum) Statistical Thermodynamics (the difference between the statistical and classical thermodynamics , statistical thermodynamics postulates , microcanonical a canonical ensemble , partition function , partition function of an ideal gas ) Phase equilibria ( molar quantities, chemical potential , chemical equilibrium in a one- phase system , fugacity, fugacity coefficient , two-phase equilibrium , Clausius - Clapeyron equation , phase diagram , partial molar quantities , Gibbs - Duhem equation , determining the partial molar quantities , chemical potential components during phase equilibrium, Gibbs phase rule , the ideal solution , the activity component in the solution , activity coefficient , Raoult law , distillation , theoretical plates of the column , gas solubility , colligative properties of solutions , cryoscopy , ebulioscopy , osmotic pressure , mixing solutions of ideal and real solutions , reference conditions , equilibrium gas - liquid at low pressures , equilibrium liquid - liquid extraction solvent Nernst law) Chemical equilibrium ( chemical equilibrium condition , reaction isotherm for unbalanced system , reactions in the gas and liquid phase , reactions in electrolyte solutions ) Content of practicals: in accordance with the lectures.
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| Learning activities and teaching methods |
Monologic (reading, lecture, briefing), Dialogic (discussion, interview, brainstorming)
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| Learning outcomes |
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The extension of knowledge of the students in area of chemical and statistical thermodynamics.
Understanding the principles of thermodynamics and equilibria a their application on solution of chemical problems |
| Prerequisites |
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Successful pass of General chemistry course
UMB/CV564 ----- or ----- UMB/564 and UMB/565 and UCH/CV104 ----- or ----- UCH/104 and UCH/121 |
| Assessment methods and criteria |
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Oral examination, Written examination
successful pass of written and oral part of the exam, 75% attendance of the exercises, student's presentation |
| Recommended literature |
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| Study plans that include the course |
| Faculty | Study plan (Version) | Category of Branch/Specialization | Recommended semester |
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